proline dl-form → HCID 57586421, compound

HRID 953886Notes

Reaction equation

HRID 953886 reaction equation
[Br:9][c:10]1[cH:11][cH:12][c:13]([CH2:14][CH2:15][O:16][Si:17]([CH3:18])([CH3:19])[C:20]([CH3:21])([CH3:22])[CH3:23])[cH:24][cH:25]1.[CH3:50][CH2:51][O:52][C:53]([CH3:54])=[O:55].[CH3:58][S:59]([CH3:60])=[O:61].[Cu:56][I:57].[K+:47].[K+:48].[K+:49].[NH:1]1[CH2:2][CH2:3][CH2:4][CH:5]1[C:6]([OH:7])=[O:8].[P:42]([O-:43])([O-:44])([O-:45])=[O:46].[c:26]1([CH:32]([CH2:33][CH2:34][NH2:35])[c:36]2[cH:37][cH:38][cH:39][cH:40][cH:41]2)[cH:27][cH:28][cH:29][cH:30][cH:31]1>>[c:10]1([NH:35][CH2:34][CH2:33][CH:32]([c:26]2[cH:27][cH:28][cH:29][cH:30][cH:31]2)[c:36]2[cH:37][cH:38][cH:39][cH:40][cH:41]2)[cH:11][cH:12][c:13]([CH2:14][CH2:15][O:16][Si:17]([CH3:18])([CH3:19])[C:20]([CH3:21])([CH3:22])[CH3:23])[cH:24][cH:25]1

Participants

9

Reactant 8

HCID 614proline dl-formHCID 679Dimethyl SulfoxideHCID 813Potassium Cation3×HCID 1061PhosphateHCID 8857Ethyl AcetateHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 796983,3-DiphenylpropylamineHCID 23254500[2-(4-Bromophenyl)ethoxy](tert-butyl)dimethylsilane

Product 1

HCID 57586421HCID 57586421, compound

Sources & evidence

ORD record
ord-92f3139dbabd4574a68832b5caab85d7
Source dataset
Validation data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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