HRID99744

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID175

Acetate

C2H3O2-

2 次

HCID923

Sodium ion

Na+

HCID961

Hydroxide

HO-

HCID6331

Borane

H3B

HCID8028

Tetrahydrofuran

C4H8O

2 次

HCID8857

Ethyl acetate

C4H8O2

HCID11776

Triphenylphosphine

C18H15P

HCID61239

Ether, ethyl ethynyl

C4H6O

HCID105144

Palladium(2+)

Pd+2

HCID58285232

2,6-Dichloro-9-{[2-(trimethylsilyl)ethoxy]methyl}-9H-purine

C11H16Cl2N4OSi

PRODUCTS

生成物

结构：CCOC=Cc1nc(Cl)nc2c1ncn2COCC[Si](C)(C)C

HCID173102862

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b2e5e73fca1647a697349bedc4d24820
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (2/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (2/10)

反应 SMILES

[BH3:11].[C:1](#[CH:2])[O:3][CH2:4][CH3:5].[C:63]([O-:64])(=[O:65])[CH3:66].[C:68]([O-:69])(=[O:70])[CH3:71].[CH3:57][CH2:58][O:59][C:60](=[O:61])[CH3:62].[Cl:12][c:13]1[n:14][c:15]([Cl:30])[c:16]2[n:17][cH:18][n:19]([CH2:22][O:23][CH2:24][CH2:25][Si:26]([CH3:27])([CH3:28])[CH3:29])[c:20]2[n:21]1.[Na+:51].[O:52]1[CH2:53][CH2:54][CH2:55][CH2:56]1.[O:6]1[CH2:7][CH2:8][CH2:9][CH2:10]1.[OH-:50].[Pd+2:67].[c:31]1([P:32]([c:33]2[cH:34][cH:35][cH:36][cH:37][cH:38]2)[c:39]2[cH:40][cH:41][cH:42][cH:43][cH:44]2)[cH:45][cH:46][cH:47][cH:48][cH:49]1>>[CH:1](=[CH:2][c:15]1[n:14][c:13]([Cl:12])[n:21][c:20]2[c:16]1[n:17][cH:18][n:19]2[CH2:22][O:23][CH2:24][CH2:25][Si:26]([CH3:27])([CH3:28])[CH3:29])[O:3][CH2:4][CH3:5]