Chloride → 2-(Di-tert-butylphosphino)biphenyl

HRID 304776

Reaction equation

HRID 304776 reaction equation
[Br:1][c:2]1[c:3](-[c:8]2[cH:9][cH:10][cH:11][cH:12][cH:13]2)[cH:4][cH:5][cH:6][cH:7]1.[CH2:27]1[O:28][CH2:29][CH2:30][CH2:31]1.[Cl-:16].[Cl:17][P:18]([C:19]([CH3:20])([CH3:21])[CH3:22])[C:23]([CH3:24])([CH3:25])[CH3:26].[I:14].[Mg:15]>>[c:2]1([P:18]([C:19]([CH3:20])([CH3:21])[CH3:22])[C:23]([CH3:24])([CH3:25])[CH3:26])[c:3](-[c:8]2[cH:9][cH:10][cH:11][cH:12][cH:13]2)[cH:4][cH:5][cH:6][cH:7]1

Participants

7

Reactant 6

HCID 312ChlorideHCID 8028TetrahydrofuranHCID 163292-BromobiphenylHCID 24841Hydrogen iodideHCID 139566Di-tert-butylchlorophosphineHCID 5462224Magnesium

Product 1

HCID 27342152-(Di-tert-butylphosphino)biphenyl

Sources & evidence

ORD record
ord-185e3121625f4fb7bc6c3372a3bfb288
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Linked notes

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