Hydrochloric Acid → 2-Propenoic acid, 3-phenyl-

HRID 22092

반응식

HRID 22092 반응식
O[C:2]1[CH:12]=[CH:11][C:5]([CH:6]=[CH:7][C:8]([OH:10])=[O:9])=[CH:4][CH:3]=1.[OH-].[K+].N#N.C1OC1CO.Cl>CS(C)=O.OCC(CO)O>[C:8]([OH:10])(=[O:9])[CH:7]=[CH:6][C:5]1[CH:4]=[CH:3][CH:2]=[CH:12][CH:11]=1

참가 물질

8

반응물 5

HCID 313Hydrochloric AcidHCID 3224-Coumaric acidHCID 947NitrogenHCID 11164GlycidolHCID 14797Potassium Hydroxide

생성물 1

HCID 87842-Propenoic acid, 3-phenyl-

시약·촉매·용매 2

HCID 679Dimethyl Sulfoxide용매HCID 753Glycerol용매

실험 절차

4.35 g of p-hydroxy cinnamic acid was dissolved in 5 ml of DMSO, and 50 mg of potassium hydroxide was added. The mixture was stirred and heated to 90° C. under flow of N2 gas. 10.0 g of glycidol was added gradually, heating and agitation was carried out for 1.5 hours, neutralized by adding hydrochloric acid and the adduct of cinnamic acid and glycerin was obtained.

후처리

  1. temperatureheating

출처 및 근거

ORD 기록
ord-542a9da6771c4edf9109f3992e977503
출처 데이터셋
uspto-grants-1995_06
특허 번호
US05426210

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