Benzaldehyde → Ethyl cinnamoylacetate

HRID 1124441Notes

Reaction equation

HRID 1124441 reaction equation
[C:30]([Cl:31])([Cl:32])([Cl:33])[Cl:34].[C:9]([CH2:10][C:11](=[O:12])[CH3:13])(=[O:14])[O:15][CH2:16][CH3:17].[CH3:18][CH2:19][N:20]([CH2:21][CH3:22])[CH2:23][CH3:24].[CH:1](=[O:2])[c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1.[Cl-:35].[Cl-:36].[Cl-:37].[Cl-:38].[O:25]1[CH2:26][CH2:27][CH2:28][CH2:29]1.[Ti+4:39]>>[CH:1]([c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1)=[CH:13][C:11]([CH2:10][C:9](=[O:14])[O:15][CH2:16][CH3:17])=[O:12]

Participants

8

Reactant 7

HCID 240BenzaldehydeHCID 312Chloride4×HCID 5943Carbon TetrachlorideHCID 8028TetrahydrofuranHCID 8471TriethylamineHCID 8868Ethyl AcetoacetateHCID 114942Titanium cation (4+)

Product 1

HCID 54004396Ethyl cinnamoylacetate

Sources & evidence

ORD record
ord-88f913785177410bbb294fb26d4ba1df
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

Loading…