1-Bromodecane → HCID 86742842, compound

HRID 1194828Notes

Reaction equation

HRID 1194828 reaction equation
[OH:1][CH:2]([CH2:11][CH:12]([OH:15])[CH2:13][CH3:14])[C:3]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=O.[CH2:16](Br)[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25].C(=O)([O-])[O-].[K+].[K+].C([O-])(=O)C.[K+].Cl.[NH2:39][OH:40]>CC(C)=O.C(O)C.O>[CH2:16]([O:15][CH:12]([CH2:13][CH3:14])[CH2:11][CH:2]([OH:1])[C:3](=[N:39][OH:40])[C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]

Participants

8

Reactant 5

HCID 81731-BromodecaneHCID 11430Potassium CarbonateHCID 443297Hydroxyamine hydrochlorideHCID 517044Potassium AcetateHCID 22610322HCID 22610322, compound

Product 1

HCID 86742842HCID 86742842, compound

Reagents, catalysts & solvents 2

HCID 180AcetoneSolventHCID 19096565Water ethanolSolvent

Procedure

20.8 g (0.1 Mol) of 2,4-dihydroxycaprophenone together with 32 g (0.145 Mol) of n-decylbromide and 14 g of anhydrous potassium carbonate in 150 ml of dried acetone, as in Example 11, were converted to ketone, between 45° C. and 47° C. in flash point, which, in absence of potassium acetate, reacted with hydroxylamine hydrochloride in ethanolic solution to oxime, 57° C. in flash point (ethanol/water).

Sources & evidence

ORD record
ord-f73dbedea9064343990bdd867586addd
Source dataset
uspto-grants-1989_03
Patent number
US04816487

Reaction notes

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