HRID1203014

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID798

Indole

C8H7N

HCID935

Nickel

HCID8028

Tetrahydrofuran

C4H8O

HCID11776

Triphenylphosphine

C18H15P

HCID14487

Diisobutylaluminum hydride

C8H19Al

HCID16272

Benzonitrile, 2-bromo-

C7H4BrN

结构：CC(C)[Si](C(C)C)(C(C)C)n1ccc2cc(Br)ccc21

HCID2794652

5-Bromo-1-[tri(propan-2-yl)silyl]-1H-indole

C17H26BrNSi

HCID178418400

未命名化合物

HCID178468203

未命名化合物

PRODUCTS

生成物

结构：CC(C)[Si](C(C)C)(C(C)C)n1ccc2cc(-c3ccccc3C#N)ccc21

HCID21468966

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b82088e68a3141eca2b32b910abbab95
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (5/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (5/10)

反应 SMILES

[Br:54][c:55]1[c:56]([C:57]#[N:58])[cH:59][cH:60][cH:61][cH:62]1.[Br:6][c:7]1[cH:8][c:9]2[cH:10][cH:11][n:12]([Si:16]([CH:17]([CH3:18])[CH3:19])([CH:20]([CH3:21])[CH3:22])[CH:23]([CH3:24])[CH3:25])[c:13]2[cH:14][cH:15]1.[CH-:78]([C:79](=[O:80])[CH3:81])[C:82](=[O:83])[CH3:84].[CH2:72]1[O:73][CH2:74][CH2:75][CH2:76]1.[CH3:45][CH:46]([CH2:47][AlH:48][CH2:49][CH:50]([CH3:51])[CH3:52])[CH3:53].[CH:1]([Li:2])([CH2:3][CH3:4])[CH3:5].[Ni:77].[c:26]1([P:27]([c:28]2[cH:29][cH:30][cH:31][cH:32][cH:33]2)[c:34]2[cH:35][cH:36][cH:37][cH:38][cH:39]2)[cH:40][cH:41][cH:42][cH:43][cH:44]1.[nH:63]1[c:64]2[c:65]([cH:66][cH:67][cH:68][cH:69]2)[cH:70][cH:71]1>>[c:7]1(-[c:55]2[c:56]([C:57]#[N:58])[cH:59][cH:60][cH:61][cH:62]2)[cH:8][c:9]2[cH:10][cH:11][n:12]([Si:16]([CH:17]([CH3:18])[CH3:19])([CH:20]([CH3:21])[CH3:22])[CH:23]([CH3:24])[CH3:25])[c:13]2[cH:14][cH:15]1