HRID134348

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8028

Tetrahydrofuran

C4H8O

HCID8471

Triethylamine

C6H15N

HCID11776

Triphenylphosphine

C18H15P

2 次

HCID24290

未命名化合物

HCID24350

Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

CuI

HCID66111

Trimethylsilylacetylene

C5H10Si

HCID22507583

未命名化合物

PRODUCTS

生成物

HCID57516761

2-Bromo-5-[(trimethylsilyl)ethynyl]pyrimidine

C9H11BrN2Si

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-6d3cc430f6204df0899af1b89fb4ed9c
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (9/10)

反应 SMILES

[Br:1][c:2]1[n:3][cH:4][c:5]([I:8])[cH:6][n:7]1.[C:9](#[CH:10])[Si:11]([CH3:12])([CH3:13])[CH3:14].[CH2:22]1[O:23][CH2:24][CH2:25][CH2:26]1.[CH3:15][CH2:16][N:17]([CH2:18][CH3:19])[CH2:20][CH3:21].[Cu:68][I:69].[Pd:27]([Cl:28])[Cl:29].[c:30]1([P:31]([c:32]2[cH:33][cH:34][cH:35][cH:36][cH:37]2)[c:38]2[cH:39][cH:40][cH:41][cH:42][cH:43]2)[cH:44][cH:45][cH:46][cH:47][cH:48]1.[c:49]1([P:50]([c:51]2[cH:52][cH:53][cH:54][cH:55][cH:56]2)[c:57]2[cH:58][cH:59][cH:60][cH:61][cH:62]2)[cH:63][cH:64][cH:65][cH:66][cH:67]1>>[Br:1][c:2]1[n:3][cH:4][c:5]([C:10]#[C:9][Si:11]([CH3:12])([CH3:13])[CH3:14])[cH:6][n:7]1