Benzaldehyde → Ethyl cinnamoylacetate

HRID 1539642Notes

Reaction equation

HRID 1539642 reaction equation
[C:1]([CH2:2][C:3](=[O:4])[CH3:5])(=[O:6])[O:7][CH2:8][CH3:9].[C:25]([Cl:26])([Cl:27])([Cl:28])[Cl:29].[CH3:18][CH2:19][N:20]([CH2:21][CH3:22])[CH2:23][CH3:24].[CH:10](=[O:11])[c:12]1[cH:13][cH:14][cH:15][cH:16][cH:17]1.[Cl-:35].[Cl-:36].[Cl-:37].[Cl-:38].[O:30]1[CH2:31][CH2:32][CH2:33][CH2:34]1.[Ti+4:39]>>[C:1]([CH2:2][C:3](=[O:4])[CH:5]=[CH:10][c:12]1[cH:13][cH:14][cH:15][cH:16][cH:17]1)(=[O:6])[O:7][CH2:8][CH3:9]

Participants

8

Reactant 7

HCID 240BenzaldehydeHCID 312Chloride4×HCID 5943Carbon TetrachlorideHCID 8028TetrahydrofuranHCID 8471TriethylamineHCID 8868Ethyl AcetoacetateHCID 114942Titanium cation (4+)

Product 1

HCID 54004396Ethyl cinnamoylacetate

Sources & evidence

ORD record
ord-a06641aaa2d44bc9a975149ae9b694e6
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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