Hydrogen Bromide → Methyl sorbate

HRID 1658900Notes

Reaction equation

HRID 1658900 reaction equation
Br.[C:2]1(P(C2C=CC=CC=2)C2C=CC=CC=2)[CH:7]=CC=C[CH:3]=1.C(O)C=C.[C:25]([O:29][CH3:30])(=[O:28])[CH:26]=[CH2:27]>C([O-])(=O)C.[Pd+2].C([O-])(=O)C>[C:25]([O:29][CH3:30])(=[O:28])/[CH:26]=[CH:27]/[CH:3]=[CH:2]/[CH3:7]

Participants

6

Reactant 4

HCID 260Hydrogen BromideHCID 7294Methyl AcrylateHCID 7858Allyl AlcoholHCID 11776Triphenylphosphine

Product 1

HCID 5323650Methyl sorbate

Reagents, catalysts & solvents 1

HCID 167845palladium(II) acetateCatalyst

Conditions

Temperature
120 °C

Procedure

A quantity of 1.1 grams palladium acetate, 0.61 cc-47° by weight hydrogen bromide, 5.25 grams triphenyl phosphine, 45 cc allyl alcohol, and 60 cc methyl acrylate is introduced into a reaction chamber and heated to 120°C for a period of 15 hours. Methyl sorbate is produced to the extent of 15% by weight of the final reaction solution.

Sources & evidence

ORD record
ord-8403e7f1fcce47118fc1e18c87fdea11
Source dataset
uspto-grants-1976_06
Patent number
US03966798

Reaction notes

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