Azobisisobutyronitrile → 2-Ethylhexanoic Acid

HRID 1808661Notes

Reaction equation

HRID 1808661 reaction equation
C([O:5][CH2:6][CH:7]([CH2:12][CH3:13])[CH2:8][CH2:9][CH2:10][CH3:11])(=O)C=C.C(N1CCCC1=[O:21])=C.C(O)(=O)C=C.N(C(C)(C)C#N)=NC(C)(C)C#N>C(OCC)(=O)C>[CH3:11][CH2:10][CH2:9][CH2:8][CH:7]([C:6]([OH:5])=[O:21])[CH2:12][CH3:13]

Participants

6

Reactant 4

HCID 6547AzobisisobutyronitrileHCID 6581Acrylic AcidHCID 6917N-vinyl-2-pyrrolidoneHCID 76362-Ethylhexyl acrylate

Product 1

HCID 86972-Ethylhexanoic Acid

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

Under an inert gas atmosphere, 72 parts by weight of 2-ethylhexyl acrylate, 25 parts by weight of N-vinyl-2-pyrrolidone, 3 parts by weight of acrylic acid, and 0.2 part by weight of azobisisobutyronitrile were added to ethyl acetate, and then the contents were mixed. The mixture was subjected to solution polymerization at 60° C. Thus, a solution (solid content: 28 w t %) of an acrylic copolymer (2-EHA/AA/N-VP=72/3/25) was obtained.

Workup

  1. additionthe contents were mixed
  2. customThe mixture was subjected to solution polymerization at 60° C

Sources & evidence

ORD record
ord-0e9f5755bc1845dbabf1d01e321474c9
Source dataset
uspto-grants-2013_01
Patent number
US08361493B2

Reaction notes

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