Diethyl Ether → Ammonia

HRID 2055821Notes

Reaction equation

HRID 2055821 reaction equation
[CH2:1]([O:3][CH2:4]C)C.[C:6]([O:10]C)([CH3:9])([CH3:8])C.O1[CH2:16][CH2:15][CH2:14][CH2:13]1.O1CCOCC1.C[N:24](C=O)C>CCCCCCC.CCCCCC.CCCCC>[C:4](=[O:3])=[O:10].[NH3:24].[CH3:13][CH2:14][CH2:15][CH2:16][CH2:1][CH2:8][CH2:6][CH3:9]

Participants

11

Reactant 5

HCID 3283Diethyl EtherHCID 6228DimethylformamideHCID 8028TetrahydrofuranHCID 15413tert-Butyl methyl etherHCID 312751,4-Dioxane

Product 3

HCID 222AmmoniaHCID 280Carbon DioxideHCID 356Octane

Reagents, catalysts & solvents 3

HCID 8003PentaneSolventHCID 8058HexaneSolventHCID 8900HeptaneSolvent

Procedure

Diethyl ether, methyl tert-butyl ether, tetrahydrofuran, dioxane, carbon dioxide (liquid or as a supercritical fluid), ammonia, pentane, hexane, heptane, octane, DMF or the mercaptoorganyl(alkoxysilanes) formed as products can very particularly preferably be employed.

Sources & evidence

ORD record
ord-3b60b78777ab476d8a29dca0649a90a1
Source dataset
uspto-grants-2008_02
Patent number
US07332619B2

Reaction notes

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