Azobisisobutyronitrile → HCID 86583984, compound

HRID 2296885Notes

Reaction equation

HRID 2296885 reaction equation
[OH:1][CH2:2][CH2:3][CH2:4][CH2:5][O:6][C:7](=[O:10])[CH:8]=[CH2:9].[CH3:11][O:12][C:13](=[O:17])[C:14]([CH3:16])=[CH2:15].CC(N=NC(C#N)(C)C)(C#N)C>C1COCC1>[OH:1][CH2:2][CH2:3][CH2:4][CH2:5][O:6][C:7](=[O:10])[CH:8]=[CH2:9].[CH3:11][O:12][C:13](=[O:17])[C:14]([CH3:16])=[CH2:15]

Participants

5

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 6658Methyl MethacrylateHCID 755884-Hydroxybutyl acrylate

Product 1

HCID 86583984HCID 86583984, compoundYield 81%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Conditions

Temperature
67.5 °C

Procedure

To a 500 ml round-bottom flask was added 0.3 mole of 9-anthracenemethylacrylate, 0.5 mole of 4-hydroxybutylacrylate, 0.2 mole of methylmethacrylate, 300 g of THF, and 0.1-3 g of AIBN. The resulting solution was stirred at 60-75° C. for 5-20 hours under nitrogen atmosphere. The reaction mixture was precipitated in ethyl ether or n-hexane. The precipitate was filtered and dried to provide poly[9-anthracenemethylacrylate/4-hydroxybutylacrylate/methylmethacrylate] copolymer of Formula 21. Yield: 81%.

Workup

  1. customThe reaction mixture was precipitated in ethyl ether
  2. filtrationThe precipitate was filtered
  3. customdried

Sources & evidence

ORD record
ord-40a3346427ec470798d4b03c832fb674
Source dataset
uspto-grants-2002_12
Patent number
US06489432B2

Reaction notes

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