Acetate → Ethyl 3-(4-cyanophenyl)prop-2-enoate

HRID 2324601Notes

Reaction equation

HRID 2324601 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([C:6]#[N:7])[cH:8][cH:9]1.[C:10]([CH:11]=[CH2:12])(=[O:13])[O:14][CH2:15][CH3:16].[C:51]([O-:52])(=[O:53])[CH3:54].[C:56]([O-:57])(=[O:58])[CH3:59].[CH3:39][CH2:40][N:41]([CH2:42][CH3:43])[CH2:44][CH3:45].[O:46]=[CH:47][N:48]([CH3:49])[CH3:50].[Pd+2:55].[c:17]1([CH3:18])[cH:19][cH:20][cH:21][cH:22][c:23]1[P:24]([c:25]1[cH:26][cH:27][cH:28][cH:29][c:30]1[CH3:31])[c:32]1[cH:33][cH:34][cH:35][cH:36][c:37]1[CH3:38]>>[c:2]1([CH:12]=[CH:11][C:10](=[O:13])[O:14][CH2:15][CH3:16])[cH:3][cH:4][c:5]([C:6]#[N:7])[cH:8][cH:9]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 6228DimethylformamideHCID 8471TriethylamineHCID 8821Ethyl AcrylateHCID 12162Benzonitrile, 4-bromo-HCID 80271Tri-o-tolylphosphineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

Product 1

HCID 367207Ethyl 3-(4-cyanophenyl)prop-2-enoate

Sources & evidence

ORD record
ord-092603379d6d457880091f7b9cff6301
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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