Methyl Methacrylate → HCID 19809267, compound

HRID 345917Notes

Reaction equation

HRID 345917 reaction equation
[C:1]1(=[O:7])[NH:5][C:4](=[O:6])[CH:3]=[CH:2]1.[C:8]([O:13][CH3:14])(=[O:12])[C:9]([CH3:11])=[CH2:10]>CN(C=O)C.CC(N=NC(C#N)(C)C)(C#N)C.C(S)CCCCCCCCCCC>[C:4]1(=[O:6])[NH:5][C:1](=[O:7])[CH:2]=[CH:3]1.[CH3:14][O:13][C:8](=[O:12])[C:9]([CH3:11])=[CH2:10]

Participants

6

Reactant 2

HCID 6658Methyl MethacrylateHCID 10935Maleimide

Product 1

HCID 19809267HCID 19809267, compoundYield 55.3%

Reagents, catalysts & solvents 3

HCID 6547AzobisisobutyronitrileCatalystHCID 81951-DodecanethiolCatalystHCID 6228DimethylformamideSolvent

Procedure

In a manner identical to Example 4, 10 g of maleimide, 10 g of methyl methacrylate, 0.8 g of AIBN, and 0.1 g of dodecanethiol were reacted in 20 g of DMF at 90° C. for 14 hr. to give 10.9 g of polymer (yield, 55% of theory). The relative viscosity, ηrel, was 1.10 (0.5 g of polymer per deciliter in dimethylformamide at 25° C.).

Sources & evidence

ORD record
ord-54054e46f14e49ae91a415a3df285364
Source dataset
uspto-grants-1991_10
Patent number
US05059513

Reaction notes

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