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HRID522428

反应详情

EQUATION

反应方程式

HRID 522428 的结构方程式

REACTANTS

反应物

4
结构：CNCCNC
HCID8070

N,N'-Dimethylethane-1,2-diamine

C4H12N2

结构：O=C([O-])[O-].[K+].[K+]
HCID11430

Potassium Carbonate

CK2O3

结构：N#Cc1ccc(Br)cc1
HCID12162

Benzonitrile, 4-bromo-

C7H4BrN

结构：CC(=O)Nc1ccc([Si](C)(C)C)cc1
HCID605997

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)N(c1ccc(C#N)cc1)c1ccc([Si](C)(C)C)cc1
HCID58536159

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Cu][I]
催化剂HCID24350

Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

CuI

结构：Cc1ccccc1C
溶剂HCID7237

o-Xylene

C8H10

PROCEDURE

实验过程

Under a flow of argon, in a 1 L-recovery flask, 27 g of N-(4-(trimethylsilyl)phenyl)acetamide, 30 g of 4-bromobenzonitrile, 6.3 g of copper (I) iodide, 45.6 g of potassium carbonate, and 412 mL of xylene were placed. After stirring, 7.1 mL of N,N′-dimethylethylenediamine was added. The resultant was heated and stirred at reflux for 18 hours.

WORKUP

后处理

  1. temperatureThe resultant was heated
  2. stirringstirred
  3. temperatureat reflux for 18 hours