Tetrahydrofuran → (3-Chlorophenylethynyl)trimethylsilane

HRID 672825Notes

Reaction equation

[CH2:34]1[O:35][CH2:36][CH2:37][CH2:38]1.[CH2:39]([N:40]([CH2:41][CH3:42])[CH2:43][CH3:44])[CH3:45].[CH3:28][Si:29]([CH3:30])([CH3:31])[C:32]#[CH:33].[Cl:1][c:2]1[cH:3][c:4]([I:8])[cH:5][cH:6][cH:7]1.[Cu:46][I:47].[c:9]1([P:10]([c:11]2[cH:12][cH:13][cH:14][cH:15][cH:16]2)[c:17]2[cH:18][cH:19][cH:20][cH:21][cH:22]2)[cH:23][cH:24][cH:25][cH:26][cH:27]1>>[Cl:1][c:2]1[cH:3][c:4]([C:33]#[C:32][Si:29]([CH3:28])([CH3:30])[CH3:31])[cH:5][cH:6][cH:7]1

Participants

Reactant 6

HCID 8028Tetrahydrofuran

HCID 8471Triethylamine

HCID 11776Triphenylphosphine

HCID 122691-Chloro-3-iodobenzene

HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

HCID 66111Trimethylsilylacetylene

Product 1

HCID 4116666(3-Chlorophenylethynyl)trimethylsilane

Sources & evidence

ORD record: ord-61fbdca9ebfa48af934d3ebff7283927
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (3/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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