Benzaldehyde → Ethyl cinnamoylacetate

HRID 680879Notes

Reaction equation

HRID 680879 reaction equation
[C:1]([CH2:2][C:3](=[O:4])[CH3:5])(=[O:6])[O:7][CH2:8][CH3:9].[C:25]([Cl:26])([Cl:27])([Cl:28])[Cl:29].[CH3:10][CH2:11][N:12]([CH2:13][CH3:14])[CH2:15][CH3:16].[CH:17](=[O:18])[c:19]1[cH:20][cH:21][cH:22][cH:23][cH:24]1.[Cl-:35].[Cl-:36].[Cl-:37].[Cl-:38].[O:30]1[CH2:31][CH2:32][CH2:33][CH2:34]1.[Ti+4:39]>>[C:1]([CH2:2][C:3](=[O:4])[CH:5]=[CH:17][c:19]1[cH:20][cH:21][cH:22][cH:23][cH:24]1)(=[O:6])[O:7][CH2:8][CH3:9]

Participants

8

Reactant 7

HCID 240BenzaldehydeHCID 312Chloride4×HCID 5943Carbon TetrachlorideHCID 8028TetrahydrofuranHCID 8471TriethylamineHCID 8868Ethyl AcetoacetateHCID 114942Titanium cation (4+)

Product 1

HCID 54004396Ethyl cinnamoylacetate

Sources & evidence

ORD record
ord-994666fae8864ab7a6d93a39d9b33c50
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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