Butyl vinyl ether → Biphenyl

HRID 914609Notes

Reaction equation

HRID 914609 reaction equation
C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.C=COCCCC.Ic1ccccc1.[Ni]>CCN(CC)CC.CN(C)C=O.CN(C)c1ccccc1-c1ccccc1P(C1CCCCC1)C1CCCCC1>C=C(OCCCC)c1ccccc1.CCCCO/C=C/c1ccccc1.CCCCO/C=C\c1ccccc1.c1ccc(-c2ccccc2)cc1

Participants

11

Reactant 2

HCID 8108Butyl vinyl etherHCID 11575Iodobenzene

Product 5

HCID 7095BiphenylHCID 693011,3,5-TrimethoxybenzeneHCID 10464845(1-Butoxyethenyl)benzeneHCID 10464846HCID 10464846, compoundHCID 13834617HCID 13834617, compound

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 27342172-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenylCatalystHCID 6228DimethylformamideSolventHCID 6433264Bis(1,5-cyclooctadiene)nickelOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-9ab5cfdf181449c8b4affe18015c83ff
Source dataset
Vinyl ether Mizoroki-Heck

Reaction notes

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