Hydrochloric Acid → 2-Propenoic acid, 3-phenyl-

HRID 22097

반응식

HRID 22097 반응식
[C:1]([O:14]C)(=[O:13])/[CH:2]=[CH:3]/[C:4]1[CH:12]=[CH:11][C:8](OC)=[C:6](O)[CH:5]=1.[H-].[Na+].C1OC1CO.Cl>CS(C)=O>[C:1]([OH:14])(=[O:13])[CH:2]=[CH:3][C:4]1[CH:5]=[CH:6][CH:8]=[CH:11][CH:12]=1

참가 물질

6

반응물 4

HCID 313Hydrochloric AcidHCID 11164GlycidolHCID 24758Sodium hydrideHCID 6439893Methyl isoferulate

생성물 1

HCID 87842-Propenoic acid, 3-phenyl-

시약·촉매·용매 1

HCID 679Dimethyl Sulfoxide용매

실험 절차

3 g of methyl isoferulate was dissolved in 600 ml of DMSO, and 370 mg of sodium hydride was added. The system was heated to 90° C. under N2 gas flow and 7 g of glycidol was added gradually. Heating and agitation was carried out for 0.5 hours. The system was cooled, neutralized by adding hydrochloric acid, solvent was removed and adduct of cinnamic acid and glycerin was obtained.

후처리

  1. additionwas added gradually
  2. temperatureHeating
  3. temperatureThe system was cooled
  4. customwas removed

출처 및 근거

ORD 기록
ord-f297ae3acb9542e7bf85a53dda6a37d2
출처 데이터셋
uspto-grants-1995_06
특허 번호
US05426210

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