Acetate → 4'-Acetoxy-5-benzyloxy-3-fluorostilbene

HRID 1115041Notes

Reaction equation

HRID 1115041 reaction equation
[C:39]([CH3:40])(=[O:41])[O:42][c:43]1[cH:44][cH:45][c:46]([CH:47]=[CH2:48])[cH:49][cH:50]1.[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][c:9]1[cH:10][c:11]([F:16])[cH:12][c:13]([Br:15])[cH:14]1.[CH3:51][CH2:52][N:53]([CH2:54][CH3:55])[CH2:56][CH3:57].[CH3:73][CH2:74][O:75][C:76]([CH3:77])=[O:78].[ClH:58].[O-:65][C:66]([CH3:67])=[O:68].[O-:69][C:70]([CH3:71])=[O:72].[O:59]=[CH:60][N:61]([CH3:62])[CH3:63].[Pd+2:64].[c:17]1([CH3:18])[cH:19][cH:20][cH:21][cH:22][c:23]1[P:24]([c:25]1[cH:26][cH:27][cH:28][cH:29][c:30]1[CH3:31])[c:32]1[cH:33][cH:34][cH:35][cH:36][c:37]1[CH3:38]>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][c:9]1[cH:10][c:11]([F:16])[cH:12][c:13]([CH:48]=[CH:47][c:46]2[cH:45][cH:44][c:43]([O:42][C:39]([CH3:40])=[O:41])[cH:50][cH:49]2)[cH:14]1

Participants

10

Reactant 9

HCID 175Acetate2×HCID 313Hydrochloric AcidHCID 6228DimethylformamideHCID 8471TriethylamineHCID 8857Ethyl AcetateHCID 758214-Ethenylphenyl acetateHCID 80271Tri-o-tolylphosphineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 112545161-(Benzyloxy)-3-bromo-5-fluorobenzene

Product 1

HCID 687420264'-Acetoxy-5-benzyloxy-3-fluorostilbene

Sources & evidence

ORD record
ord-557c437e6987449ba9cb8c40527b030b
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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