Dimethylformamide → HCID 67163892, compound

HRID 90961Notes

Reaction equation

HRID 90961 reaction equation
[C:1]([CH3:2])(=[O:3])[O:4][CH:5]1[CH:6]([CH2:28][O:29][Si:30]([CH3:31])([CH3:32])[C:33]([CH3:34])([CH3:35])[CH3:36])[O:7][CH:8]([n:10]2[cH:11][c:12]([I:27])[c:13]3[c:14]2[n:15][cH:16][n:17][c:18]3[CH2:19][CH2:20][c:21]2[cH:22][cH:23][cH:24][cH:25][cH:26]2)[CH2:9]1.[C:46](#[CH:47])[Si:48]([CH3:49])([CH3:50])[CH3:51].[CH3:57][CH2:58][O:59][C:60]([CH3:61])=[O:62].[CH:37]([N:38]([CH2:39][CH3:40])[CH:41]([CH3:42])[CH3:43])([CH3:44])[CH3:45].[Cu:63][I:64].[O:52]=[CH:53][N:54]([CH3:55])[CH3:56].[Pd:65]([Cl:66])[Cl:67].[c:68]1([P:69]([c:70]2[cH:71][cH:72][cH:73][cH:74][cH:75]2)[c:76]2[cH:77][cH:78][cH:79][cH:80][cH:81]2)[cH:82][cH:83][cH:84][cH:85][cH:86]1.[c:87]1([P:88]([c:89]2[cH:90][cH:91][cH:92][cH:93][cH:94]2)[c:95]2[cH:96][cH:97][cH:98][cH:99][cH:100]2)[cH:101][cH:102][cH:103][cH:104][cH:105]1>>[C:1]([CH3:2])(=[O:3])[O:4][CH:5]1[CH:6]([CH2:28][O:29][Si:30]([CH3:31])([CH3:32])[C:33]([CH3:34])([CH3:35])[CH3:36])[O:7][CH:8]([n:10]2[cH:11][c:12]([C:47]#[C:46][Si:48]([CH3:49])([CH3:50])[CH3:51])[c:13]3[c:14]2[n:15][cH:16][n:17][c:18]3[CH2:19][CH2:20][c:21]2[cH:22][cH:23][cH:24][cH:25][cH:26]2)[CH2:9]1

Participants

9

Reactant 8

HCID 6228DimethylformamideHCID 8857Ethyl AcetateHCID 11776Triphenylphosphine2×HCID 24290Palladium ChlorideHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 66111TrimethylsilylacetyleneHCID 81531DiisopropylethylamineHCID 67163819[2-[[Tert-butyl(dimethyl)silyl]oxymethyl]-5-[5-iodo-4-(2-phenylethyl)pyrrolo[2,3-d]pyrimidin-7-yl]oxolan-3-yl] acetate

Product 1

HCID 67163892HCID 67163892, compound

Sources & evidence

ORD record
ord-2aa0660a2b38403e8e674e21c3caaf9d
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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